Mid Infrared near field microscopy

Supervisor: Dr Ben Murdin


Major Aims:
To develop a near field microscope working in the mid-infrared region of the spectrum, for use in semiconductor physics and bio/medical/chemical applications


Techniques used and source of expertise:
Mid-infrared spectroscopy will be used in conjunction with an atomic force microscope, to develop false colour images on a sub-micron scale while using light of wavelength several microns.


Mid-infrared spectroscopy is very useful in the fields of semiconductor physics and elsewhere, in particular due to the different vibrational frequencies which different chemical bonds produce. It enables detection of molecular species and this is important for a broad range of applications. At present, this has only been possible on “macroscopic” samples (such as gas samples in pollution monitoring), because the smallest thing it is possible to detect with a given wavelength is normally several times the size of the wavelength of the light used. However, a new technique called near field optical microscopy has been developed for the visible region of the spectrum, in which photons “tunnel” out of the end of an optical fibre which has been drawn to a point much smaller than the wavelength. This has enabled images to be taken with resolution down to 1/100th the wavelength.
Such microscopes for the mid-infrared region of the spectrum have not so far been developed due to the lack of suitable laser sources in that region. Using recently available semiconductor lasers, we would like to develop an instrument based on an idea recently published in Nature, involving an Atomic Force Microscope, which will give surface relief information as well as the identification of the molecules.
The microscope will be used specifically to investigate new quantum dot semiconductor structures, and the ordering of polymers. New samples and applications, e.g. in biochemistry, are likely to arise in the course of the project, which is open ended and depends on the interest of the student.


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